| # | Date | Promotion | Match |
| 1 | 10.01.2006 |  |
World Heavyweight Title 20 Man Battle Royal (vakant): Kurt Angle defeats Brian Kendrick and John Bradshaw Layfield and Lashley and Mark Henry and Matt Hardy and Mercury and Nitro and Nunzio and Orlando Jordan and Paul Burchill and Paul London and Psicosis and Rey Mysterio and Road Warrior Animal and Simon Dean and Super Crazy and Sylvan and Vito and William Regal (23:57) - TITLE CHANGE !!! WWE Friday Night SmackDown #335 - TV-Show @ Wachovia Arena in Philadelphia, Pennsylvania, USA |
| 2 | 29.01.2006 |  |
Royal Rumble: Rey Mysterio defeats Booker T and Carlito and Chavo Guerrero and Chris Benoit and Chris Masters and Eugene and Goldust and Jonathan Coachman and Kane and Lashley and Matt Hardy and Mercury and Nitro and Orlando Jordan and Psicosis and Randy Orton and Ric Flair and Road Warrior Animal and Rob Van Dam and Shawn Michaels and Shelton Benjamin and Simon Dean and Super Crazy and Sylvan and Tatanka and The Big Show and Trevor Murdoch and Triple H and Viscera (62:28) WWE Royal Rumble 2006 - Pay Per View @ AmericanAirlines Arena in Miami, Florida, USA |
| 3 | 30.01.2006 | |
Mark Henry & Randy Orton defeat Kurt Angle & Rey Mysterio (12:54) WWE Friday Night SmackDown #338 - TV-Show @ TD Waterhouse Center in Orlando, Florida, USA |
| 4 | 19.02.2006 | |
WrestleMania Main Event Spot On The Line: Randy Orton defeats Rey Mysterio (17:25) WWE No Way Out 2006 - Pay Per View @ First Mariner Arena in Baltimore, Maryland, USA |
| 5 | 21.02.2006 | |
Bobby Lashley, Chris Benoit & Rey Mysterio defeat Finlay, John Bradshaw Layfield & Randy Orton (15:54) WWE Friday Night SmackDown #341 - TV-Show @ Richmond Coliseum in Richmond, Virginia, USA |
| 6 | 07.03.2006 | |
Kurt Angle & Rey Mysterio defeat Mark Henry & Randy Orton by DQ (0:13) WWE Friday Night SmackDown #343 - TV-Show @ Civic Center in Mobile, Alabama, USA |
| 7 | 14.03.2006 | |
Kurt Angle, Randy Orton & Rey Mysterio defeat Mark Henry & MNM (Mercury & Nitro) WWE Friday Night SmackDown #344 - TV-Show @ CenturyTelCenter in Bossier City, Louisiana, USA |
| 8 | 18.03.2006 |  |
Three On Two Handicap: John Cena & Triple H defeat Kurt Angle, Randy Orton & Rey Mysterio (11:42) WWE Saturday Night's Main Event #32 - TV-Show @ Cobo Arena in Detroit, Michigan, USA |
| 9 | 28.03.2006 | |
Kurt Angle defeats Rey Mysterio (15:23) WWE Friday Night SmackDown #346 - TV-Show @ Kemper Arena in Kansas City, Missouri, USA |
| 10 | 02.04.2006 | |
World Heavyweight Title Triple Threat: Rey Mysterio defeats Kurt Angle (c) and Randy Orton (9:25) - TITLE CHANGE !!! WWE WrestleMania 22 - "Big Time" - Pay Per View @ Allstate Arena in Rosemont, Illinois, USA |
| 11 | 04.04.2006 | |
World Heavyweight Title: Rey Mysterio (c) defeats Randy Orton (21:36) WWE Friday Night SmackDown #347 - TV-Show @ Civic Center in Peoria, Illinois, USA |
| 12 | 11.04.2006 | |
King Of The Ring 2006 First Round: Kurt Angle defeats Randy Orton (8:13) WWE Friday Night SmackDown #348 - TV-Show @ Resch Center in Green Bay, Wisconsin, USA |
| 13 | 22.04.2006 | |
World Heavyweight Title: Rey Mysterio (c) vs. Kurt Angle - No Contest (14:49) WWE Friday Night SmackDown #350 - TV-Show @ Wembley Arena in London, England, UK |
